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Objectives · Part 16

Chapter 2: structure of atom · CHEMISTRY

This means that red radiation is most intense at a particular temperature and the blue radiation is more intense at another temperature. This means intensities of radiations of different wavelengths emitted by hot body depend upon its temperature. By late ’s it was known that objects made of different material and kept at different temperatures emit different amount of radiation. Also, when the surface of an object is irradiated with light (electromagnetic radiation), a part of radiant energy is generally reflected as such, a part is absorbed and a part of it is transmitted.

The reason for incomplete absorption is that ordinary objects are as a rule imperfect absorbers of radiation. An ideal body, which emits and absorbs radiations of all frequencies uniformly, is called a black body and the radiation emitted by such a body is called black body radiation. In practice, no such body exists. Carbon black approximates fairly closely to black body.

A good physical approximation to a black body is a cavity with a tiny hole, which has no other opening. Any ray by making an assumption that absorption and emmission of radiation arises from oscillator i.e., atoms in the wall of black body. Their frequency of oscillation is changed by interaction with oscilators of electromagnetic radiation. Planck assumed that radiation could be sub-divided into discrete chunks of energy.

He suggested that atoms and molecules could emit or absorb energy only in discrete quantities and not in a continuous manner. He gave the name quantum to the smallest quantity of energy that can be emitted or absorbed in the form of electromagnetic radiation. The energy ( E ) of a quantum of radiation is proportional to its frequency ( ν ) and is expressed by equation ( . ).

E = h υ ( . ) The proportionality constant, ‘ h ’ is known as Planck’s constant and has the value . × – J s. With this theory, Planck was able to explain the distribution of intensity in the radiation from black body as a function of frequency or wavelength at different temperatures.

Quantisation has been compared to standing

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