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Objectives · Part 17

Chapter 2: structure of atom · CHEMISTRY

on a staircase. A person can stand on any step of a staircase, but it is not possible for him/her to stand in between the two steps. The energy can take any one of the values from the following set, but cannot take on any values between them. E = , h υ , h υ , h υ ....

nh υ ..... Photoelectric Effect In , H. Hertz performed a very interesting experiment in which electrons (or electric current) were ejected when certain metals (for example potassium, rubidium, caesium etc.) were exposed to a beam of light as shown in Fig. .

. The phenomenon is called Photoelectric effect . The results observed in this experiment were: (i) The electrons are ejected from the metal surface as soon as the beam of light strikes the surface, i.e., there is no time lag between the striking of light beam and the ejection of electrons from the metal surface. (ii) The number of electrons ejected is proportional to the intensity or brightness of light.

(iii) For each metal, there is a characteristic minimum frequency, ν (also known as threshold frequency ) below which photoelectric effect is not observed. At a frequency ν > ν , the ejected electrons come out with certain kinetic energy. The kinetic energies of these electrons increase with the increase of frequency of the light used. All the above results could not be explained on the basis of laws of classical physics.

According to latter, the energy content of the beam of light depends upon the brightness of the light. In other words, number of electrons ejected and kinetic energy associated with them should depend on the brightness of light. It has been observed that though the number Fig. .

Equipment for studying the photoelectric effect. Light of a particular frequency strikes a clean metal surface inside a vacuum chamber. Electrons are ejected from the metal and are counted by a detector that measures their kinetic energy. Max Planck ( – ) Max Planck, a German physicist, received his Ph.D in theoretical physics from the University of

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