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Objectives · Part 19

Chapter 2: structure of atom · CHEMISTRY

idea that light possesses both particle and wave-like properties, i.e., light has dual behaviour. Depending on the experiment, we find that light behaves either as a wave or as a stream of particles. Whenever radiation interacts with matter, it displays particle like properties in contrast to the wavelike properties (interference and diffraction), which it exhibits when it propagates. This concept was totally alien to the way the scientists thought about matter and radiation and it took them a long time to become convinced of its validity.

It turns out, as you shall see later, that some microscopic particles like electrons also exhibit this wave- particle duality. Shining a beam of light on to a metal surface can, therefore, be viewed as shooting a beam of particles, the photons. When a photon of sufficient energy strikes an electron in the atom of the metal, it transfers its energy instantaneously to the electron during the collision and the electron is ejected without any time lag or delay. Greater the energy possessed by the photon, greater will be transfer of energy to the electron and greater the kinetic energy of the ejected electron.

In other words, kinetic energy of the ejected electron is proportional to the frequency of the electromagnetic radiation. Since the striking photon has energy equal to h ν and Table . Values of Work Function (W ) for a Few Metals Metal Li Na K Mg Cu Ag W /eV . .

Albert Einstein, a German born American physicist, is regarded by many as one of the two great physicists the world has known (the other is Isaac Newton). His three research papers (on special relativity, Brownian motion and the photoelectric effect) which he published in , while he was employed as a technical assistant in a Swiss patent office in Berne have profoundly influenced the development of physics. He received the Nobel Prize in Physics in for his explanation of the photoelectric effect. Albert Einstein ( – ) Problem .

Calculate energy of one mole of photons of radiation whose frequency is

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