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Objectives · Part 61

Chapter 2: structure of atom · CHEMISTRY

Bohr orbit to the fifth Bohr orbit and what is the wavelength of the light emitted when the electron returns to the ground state? The ground state electron energy is – . × – ergs. .

The electron energy in hydrogen atom is given by E n = (– . × – )/ n J. Calculate the energy required to remove an electron completely from the n = orbit. What is the longest wavelength of light in cm that can be used to cause this transition?

. Calculate the wavelength of an electron moving with a velocity of . × m s – . .

The mass of an electron is . × – kg. If its K.E. is .

× – J, calculate its wavelength. . Which of the following are isoelectronic species i.e., those having the same number of electrons? Na + , K + , Mg + , Ca + , S – , Ar.

. (i) Write the electronic configurations of the following ions: (a) H– (b) Na+ (c) O2– (d) F– (ii) What are the atomic numbers of elements whose outermost electrons are represented by (a) 3s1 (b) 2p3 and (c) 3p5 ? (iii) Which atoms are indicated by the following configurations ? (a) [He] s (b) [Ne] s p (c) [Ar] s d .

. What is the lowest value of n that allows g orbitals to exist? . An electron is in one of the d orbitals.

Give the possible values of n , l and m l for this electron. . An atom of an element contains electrons and neutrons. Deduce (i) the number of protons and (ii) the electronic configuration of the element.

. Give the number of electrons in the species . (i) An atomic orbital has n = . What are the possible values of l and ml ?

(ii) List the quantum numbers ( ml and l ) of electrons for 3d orbital. (iii) Which of the following orbitals

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