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1.2  Concentration of ores

Chapter 1: Chapter 1 · CHEMISTRY-VOLUME 1

. Concentration of ores Generally, the ores are associated with nonmetallic impurities, rocky materials and siliceous matter which are collectively known as gangue. The preliminary step in metallurgical process is removal of these impurities. This removal process is known as concentration of ore.

It increases the concentration of the metal of interest or its compound in the ore. Several methods are available for this process and the choice of method will depend on the nature of the ore, type of impurity and environmental factors. Some of the common methods of ore concentration are discussed below. .

. Gravity separation or Hydraulic wash In this method, the ore having high specific gravity is separated from the gangue that has low specific gravity by simply washing with running water. Ore is crushed to a finely powdered form and treated with rapidly flowing current of water. During this process the lighter gangue particles are washed away by the running water.

This method is generally applied to concentrate the native ore such as gold and oxide ores such as haematite (Fe O ), tin stone (SnO ) etc. XII U1 Metallurgy - XII U1 Metallurgy - - - - - . . Froth flotation This method is commonly used to concentrate sulphide ores such as galena (PbS), zinc blende (ZnS) etc...

In this method, the metallic ore particles which are preferentially wetted by oil can be separated from gangue. In this method, the crushed ore is suspended in water and mixed with frothing agent such as pine oil, eucalyptus oil etc. A small quantity of sodium ethyl xanthate which acts as a collector is also added. A froth is generated by blowing air through this mixture.

The collector molecules attach to the ore particle and make them water repellent. As a result, ore particles, wetted by the oil, rise to the surface along with the froth. The froth is skimmed off and dried to recover the concentrated ore. The gangue particles that are preferentially wetted by water settle at the bottom.

When a sulphide ore of a metal of

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