. D IELECTRICS AND P OLARISATION Dielectrics are non-conducting substances. In contrast to conductors, they have no (or negligible number of ) charge carriers. Recall from Section .
what happens when a conductor is placed in an external electric field. The free charge carriers move and charge distribution in the conductor adjusts itself in such a way that the electric field due to induced charges opposes the external field within the conductor. This happens until, in the static situation, the two fields cancel each other and the net electrostatic field in the conductor is zero. In a dielectric, this free movement of charges is not possible.
It turns out that the external field induces dipole moment by stretching or re-orienting molecules of the dielectric. The collective effect of all the molecular dipole moments is net charges on the surface of the dielectric which produce a field that opposes the external field. Unlike in a conductor, however, the opposing field so induced does not exactly cancel the external field. It only reduces it.
The extent of the effect depends on the nature of the dielectric. To understand the effect, we need to look at the charge distribution of a dielectric at the molecular level. The molecules of a substance may be polar or non-polar. In a non-polar molecule, the centres of positive and negative charges coincide.
The molecule then has no permanent (or intrinsic) dipole moment. Examples of non-polar molecules are oxygen (O ) and hydrogen (H ) molecules which, because of their symmetry, have no dipole moment. On the other hand, a polar molecule is one in which the centres of positive and negative charges are separated (even when there is no external field). Such molecules have a permanent dipole moment.
An ionic molecule such as HCl or a molecule of water (H O) are examples of polar molecules. FIGURE . Difference in behaviour of a conductor and a dielectric in an external electric field. FIGURE .
Some examples of polar and non-polar molecules. In an external electric field, the positive and negative charges of a